NASA’s Curiosity Rover detects Methane, Organics on Mars

On Tuesday, December 16, 2014, NASA scientists attending the American Geophysical Union Fall Meeting in San Francisco announced the detection of organic compounds on Mars. The announcement represents the discovery of the missing “ingredient” that is necessary for the existence – past or present – of life on Mars.

Indeed, the extraordinary claim required extraordinary evidence – the famous assertion of Dr. Carl Sagan. The scientists, members of the Mars Science Lab – Curiosity Rover – mission, worked over a period of 20 months to sample and analyze Martian atmospheric and surface samples to arrive at their conclusions. The announcement stems from two separate detections of organics: 1) ten-fold spikes in atmospheric Methane levels, and 2) drill samples from a rock called Cumberland which included complex organic compounds.

The Tunable Laser Spectrometer, one of the tools within the Sample Analysis at Mars (SAM) laboratory on NASA’s Curiosity Mars rover. By measuring absorption of light at specific wavelengths, it measures concentrations of methane, carbon dioxide and water vapor in Mars’ atmosphere. (Image Credit: NASA/JPL-Caltech)

Methane, of the simplest organic compounds, was detected using the Sample Analysis at Mars instrument (SAM). This is one of two compact laboratory instruments embedded inside the compact car-sized rover, Curiosity. Very soon after landing on Mars, the scientists began to use SAM to periodically measure the chemical content of the Martian atmosphere. Over many samples, the level of Methane was very low, ~0.9 parts per billion. However, that suddenly changed and, as scientists stated in the press conference, it was a “wow” moment that took them aback. Brief daily spikes in Methane levels averaging 7 parts per billion were detected.

The detection of methane at Mars has been claimed for decades, but more recently, in 2003 and 2004, independent research teams using sensitive spectrometers on Earth detected methane in the atmosphere of Mars. One group led by Vladimir Krasnopolsky of Catholic University, and another led by Dr. Michael Mumma from NASA Goddard Space Flight Center, detected broad regional and temporal levels of Methane as high as 30 parts per billion. Those announcements met with considerable skepticism from the scientific community. And the first atmospheric measurements by Curiosity were negative. However, neither group backed down from their claims.

Regions where methane appears notably localized in Northern Summer (A, B1, B2), and their relationship to mineralogical and geo-morphological domains. (A.) Observations of methane near the Syrtis Major volcanic district. (B.) Geologic map of Greeley and Guest (41) superimposed on the topographic shaded-relief from MOLA (42). The most ancient terrain (Npld, Nple) is Noachian in age (~3.6 – 4.5 billion years old, when Mars was wet), and is overlain by volcanic deposits from Syrtis Major of Hesperian (Hs) age (~3.1 – 3.6 billion yrs old). (Credit: Mumma, et al., 2009, Figure 3)

The sudden detection of ten-fold spikes in methane levels in Gale crater is not inconsistent with the earlier remote measurements from Earth. The high seasonal concentrations were in regions that do not include Gale Crater, and it remains possible that the Curiosity measurements are of a similar nature but due to some less active process than exists at the regions identified by Dr. Mumma’s team.

This graphic shows tenfold spiking in the abundance of methane in the Martian atmosphere surrounding NASA’s Curiosity Mars rover, as detected by a series of measurements made with the Tunable Laser Spectrometer instrument in the rover’s Sample Analysis at Mars laboratory suite. (Image Credit: NASA/JPL-Caltech)

The NASA scientists at AGU led by MSL project scientist Dr. John Grotzinger emphasized that they do not yet know how the methane is being generated. The process could be biological or not. There are abiotic chemical processes that could produce methane. However, the MSL SAM detections were daily spikes and represent an active real on-going process on the red planet. This alone is a very exciting aspect of the detection.

The team presented slides to describe how methane could be generated. With the known low background levels of methane at ~ 1 part per billion, an external cosmic source, for example micro-meteoroids entering the atmosphere and releasing organics which is then reduced by sunlight to methane, could be ruled out. The methane source must be of local origin.

This image illustrates possible ways methane might be added to Mars’ atmosphere (sources) and removed from the atmosphere (sinks). NASA’s Curiosity Mars rover has detected fluctuations in methane concentration in the atmosphere, implying both types of activity occur on modern Mars. A longer caption discusses which are sources and which are sinks. (Image Credit: NASA/JPL-Caltech/SAM-GSFC/Univ. of Michigan)

The scientists illustrated two means of production. In both instances, there is some daily – or at least periodic – activity that is releasing methane from the subsurface of Mars. The source could be biological which is accumulated in subsurface rocks then suddenly released. Or an abiotic chemistry, such as a reaction between the mineral olivine and water, could be the generator.

The subsurface storage mechanism of methane proposed and illustrated is called clathrate storage. Clathrate storage involves lattice compounds that can trap molecules such as methane which can subsequently be released by physical changes in the clathrate, such as solar heating or mechanical stresses. Through press Q&A, the NASA scientists stated that such clathrates could be preserved for millions and billions of years underground.

The second discovery of organics involved more complex compounds in surface materials. Also since arriving at Mars, Curiosity has utilized a drilling tool to probe the interiors of rocks. Grotzinger emphasized how material immediately at the surface of Mars has experienced the effects of radiation and the ubiquitous soil compound perchlorate reducing and destroying organics both now and over millions of years. The detection of no organics in loose and exposed surface material had not diminished NASA scientists’ hopes of detecting organics in the rocks of Mars.

Comparisons between the amount of an organic chemical named chlorobenzene detected in the “Cumberland” rock sample and amounts of it in samples from three other Martian surface targets analyzed by NASA’s Curiosity Mars rover. (Image Credit: NASA/JPL-Caltech)

Drilling was performed on several selected rocks and it was finally a mud rock called Cumberland that revealed the presence of organic compounds more complex than simple methane. The scientists did emphasize that what exactly these organic compounds are remains a mystery because of the confounding presence of the active chemical perchlorate which can quickly breakdown organics to simpler forms.

Examples from the Sample Analysis at Mars (SAM) laboratory’s detection of Martian organics in a sample of powder that the drill on NASA’s Curiosity Mars rover collected from a rock target called “Cumberland.”
(Image Credit: NASA/JPL-Caltech)

The detection of organics in the mud rock Cumberland required the drilling tool and also the scoop on the multifaceted robotic arm to deliver the sample into the SAM laboratory for analysis. To detect methane, SAM has an intake valve to receive atmospheric samples.

Dr. Grotzinger described how Cumberland was chosen as a sample source. The rock is called a mud stone which has undergone a process called digenesis – the metamorphosis of sediment to rock. Grotzinger emphasized that fluids will move through such rock during digenesis and perchlorate can destroy organics in the process. Such might be the case for many metamorphic rocks on the Martian surface. The panel of scientists showed a comparison between rock samples measured by SAM. Two in particular – from the rock “John Klein” and the Cumberland rock — were compared. The former showed no organics as well as other rocks that were sampled; but Cumberland’s drill sample from its interior did reveal organics.

Illustration of some of the reasons why finding organic chemicals on Mars is challenging. Whatever organic chemicals may be produced on Mars or delivered to Mars face several possible modes of being transformed or destroyed. (Image Credit: NASA/JPL-Caltech)

The analysis of the work was painstaking – harking back to the Sagan statement. The importance of discovering organics on Mars could not be understated by the panel of scientists and Grotzinger called these two discoveries as the lasting legacy of the Mars Curiosity Rover. Furthermore, he stated that the discovery and analysis methods will go far to guide the choice of instruments and their use during the Mars 2020 rover mission.

The discovery of organics completes the necessary set of “ingredients” for past or present life on Mars: 1) an energy source, 2) water, and 3) organics. These are the basic requirements for the existence of life as we know it. The search for life on Mars is still just beginning and the new discoveries of organics is still not a clear sign that life existed or is present today. Nevertheless, Dr. Jim Green, introducing the panel of scientists, and Dr. Grotzinger both emphasized the magnitude of these discoveries and how they are tied into the objectives of the NASA Mars program — particularly now with the emphasis on sending humans to Mars. For the Mars Curiosity rover, the journey up the slopes of Mount Sharp continues and now with greater earnestness and a continued search for rocks similar to Cumberland.


Curiosity detects methane spike on Mars

NASA Rover Finds Active, Ancient Organic Chemistry on Mars

Research Papers, AGU Press Conerence via Ustream

Strong Release of Methane on Mars in Northern Summer 2003

Non-Detection of Methane in the Mars Atmosphere by the Curiosity Rover

Detection of methane in the martian atmosphere: evidence for life?

Tim Reyes

Contributing writer Tim Reyes is a former NASA software engineer and analyst who has supported development of orbital and lander missions to the planet Mars since 1992. He has an M.S. in Space Plasma Physics from University of Alabama, Huntsville.

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