The Ozone Hole is Definitely Recovering

A view of Earth's atmosphere from space. Credit: NASA

The ozone layer is a integral part of what makes Earth habitable. This region of the stratosphere is responsible for absorbing the majority of the Sun’s ultraviolet radiation, thus ensuring terrestrial organisms are not irradiated. Since the 1970s, scientists became aware of a steady decline in this layer around the southern polar region, along with and a major seasonal decrease. This latter phenomena, known as the “ozone hole”, has been a major concern for decades.

Attempts to remedy this situation have focused on cutting the use of industrial chemicals, such as chlorofluorocarbons (CFCs). These efforts culminated with the signing of the Montreal Protocol in 1987, which called for the complete phasing out of ozone-depleting substances (ODSs). And according to recent study by a team of NASA scientists, the ozone hole is showing signs of significant recovery as a result.

The study, titled “Decline in Antarctic Ozone Depletion and Lower Stratospheric Chlorine Determined From Aura Microwave Limb Sounder Observations“, recently appeared in the scientific journal Geophysical Research Letters. The study was led by Susan E Strahan and co-authored by Anne R. Douglass, two research scientists with NASA Goddard’s Atmospheric Chemistry and Dynamics Laboratory.

Artist’s impression of the Aura satellite. Credit: NASA

For the sake of their study, the team consulted data from NASA’s Aura satellite, which has been monitoring the southern polar region since 2005. Having launched in 2004, the purpose of the Aura satellite was to conduct measurements of ozone, aerosols and key gases in the Earth’s atmosphere. And according to the readings it has gathered since 2005, the reductions in the use of CFCs has led to a 20% decrease in ozone depletion.

Simply put, CFCs are long-lived chemical compounds that are made up of carbon, chlorine, and fluorine. Since the latter half of the 20th century, they have been used in a number of industrial applications such as refrigeration (as Freon), in chemical aerosols (as propellants), and as solvents. Eventually, these chemicals rise into the stratosphere where they become subject to UV radiation and are broken down into chlorine atoms.

These chlorine atoms play havoc with the ozone layer, where they catalyze to form oxygen gas (O²). This activity begins around July during the Southern Hemisphere’s winter, when the Sun’s rays cause an increase in the catalyzing of CFC-derived chlorine and bromine atoms in the atmosphere. By September (i.e. spring in the southern hemisphere), the activity peaks, resulting on the “ozone hole” that scientists first noted in 1985.

In the past, statistical analysis studies have indicated that ozone depletion has increased since. However, this study – which was the first to use measurements of the chemical composition inside the ozone hole – indicated that ozone depletion is decreasing. What’s more, it indicated that the decrease is caused by the decline in CFC use.

As Susan Strahan explained in a recent NASA press release, “We see very clearly that chlorine from CFCs is going down in the ozone hole, and that less ozone depletion is occurring because of it.” To determine how ozone and other chemicals in the atmosphere have changed from year to year, scientists have relied on data from the Aura satellite’s Microwave Limb Sounder (MLS).

Unlike other instruments that rely on sunlight to obtain spectra from atmospheric gases, this instrument measures these gases respective microwave emissions. As a result, it can measure trace gases over Antarctica during a key time of the year – when the southern hemisphere is experiencing winter and weather in the stratosphere is calm and temperatures are low and stable.

The change in ozone levels from the beginning to the end of Southern Hemisphere’s winter (early July to mid-September) was computed daily using MLS measurements every year from 2005 to 2016. While these measurements indicated a decrease in ozone loss, Strahan and Douglass wanted to be certain reductions in the use of CFCs was what was responsible.

This they did by looking for telltale signs of hydrochloric acid in the MLS data, which chlorine will form by reacting with methane (but only when all available ozone is depleted). As Strahan explained:

“During this period, Antarctic temperatures are always very low, so the rate of ozone destruction depends mostly on how much chlorine there is. This is when we want to measure ozone loss… By around mid-October, all the chlorine compounds are conveniently converted into one gas, so by measuring hydrochloric acid we have a good measurement of the total chlorine.”

Images from the Ozone Monitoring Instrument (OMI) on NASA’s Aura satellite showing ozone fluctuations between 2010 and 2011. Credit: NASA/Rob Simmon

Another hint came in the form of nitrous oxide levels, another long-lived gas that behaves just like CFCs in much of the stratosphere – but which is not in decline like CFCs. If CFCs in the stratosphere were decreasing, it would mean that less chlorine would be present compared to nitrous oxide. By comparing MLS measurements of hydrochloric acid and nitrous oxide each year, they determined that chlorine levels were declining by about 0.8 percent per year.

As Strahan indicated, this added up to a 20% decrease from 2005 to 2016, which was consistent with what they expected. “This is very close to what our model predicts we should see for this amount of chlorine decline,” she said. “This gives us confidence that the decrease in ozone depletion through mid-September shown by MLS data is due to declining levels of chlorine coming from CFCs. But we’re not yet seeing a clear decrease in the size of the ozone hole because that’s controlled mainly by temperature after mid-September, which varies a lot from year to year.”

This process of recovery is expected to continue as CFCs gradually leave the atmosphere, though scientists anticipate that a complete recovery will take decades. This is very good news considering that the ozone hole was discovered only about three decades ago, and ozone levels began to stabilize about a decade later. Still, as Douglass explained, a full recovery is not likely to take place until the latter half of this century:

“CFCs have lifetimes from 50 to 100 years, so they linger in the atmosphere for a very long time. As far as the ozone hole being gone, we’re looking at 2060 or 2080. And even then there might still be a small hole.”

The Montreal Protocol is often touted as an example of effective international climate action, and for good reason. The Protocol was struck thirteen years after the scientific consensus on ozone depletion was reached, and just two years after the rather alarming discovery of the ozone hole. And in the years that followed, the signatories remained committed to their goals and achieved target reductions.

In the future, it is hoped that similar action can be achieved on climate change, which has been subject to delays and resistance for many years now. But as the case of the ozone hole demonstrates, international action can address a problem before it is too late.

Further Reading: NASA

Saturn’s Mysterious Hexagon Behaves Like Earth’s Ozone Hole

At Saturn, NASA's Cassini spacecraft snapped pictures showing a high-resolution view of a hexagon-shaped jet stream. Credit: NASA/JPL-Caltech/SSI/Hampton

A raging hurricane is creating a “suck zone” at Saturn’s north pole. The handy Cassini spacecraft recently captured a bunch of images of the six-sided jet stream surrounding the storm, which mission managers then put together into an awesome animation showing the wind currents shifting. (You can see the animation below the jump.)

The feature is pretty in a picture, but NASA has a special interest because there is nothing else like this anywhere in our solar system, the agency stated. The immense storm stretches 20,000 miles (30,000 kilometers) across with winds whipping in its jet stream at 200 miles per hour (322 kilometers per hour). And despite all the turbulence, the storm is staying put at the north pole for reasons scientists are still trying to understand.

“The hexagon is just a current of air, and weather features out there that share similarities to this are notoriously turbulent and unstable,” said Andrew Ingersoll, a Cassini imaging team member at the California Institute of Technology in Pasadena. “A hurricane on Earth typically lasts a week, but this has been here for decades — and who knows — maybe centuries.”

An animation of Cassini Saturn images showing a hexagonal jet stream surrounding a storm at the north pole. Credit: NASA/JPL-Caltech/SSI/Hampton University
An animation of Cassini Saturn images showing a hexagonal jet stream surrounding a storm at the north pole. Credit: NASA/JPL-Caltech/SSI/Hampton University

Cassini has been orbiting Saturn since 2004, but it’s only since last year that it’s been able to peer at the hexagon with much success. That’s because the angle of the sun is finally favorable to peer at the storm. This has allowed scientists, for example, to look at the types of particles inside. They discovered that the jet stream is a sort of barrier around the storm, delineating a location with a lot of small haze particles and few large haze particles. (It’s the opposite outside of the jet stream). Scientists said it looks like the Antarctic ozone hole on Earth.

“The Antarctic ozone hole forms within a region enclosed by a jet stream with similarities to the hexagon,” NASA stated.

“Wintertime conditions enable ozone-destroying chemical processes to occur, and the jet stream prevents a resupply of ozone from the outside. At Saturn, large aerosols cannot cross into the hexagonal jet stream from outside, and large aerosol particles are created when sunlight shines on the atmosphere. Only recently, with the start of Saturn’s northern spring in August 2009, did sunlight begin bathing the planet’s northern hemisphere.”

Should Cassini have enough funding to function for a few more years, scientists are eager to watch as Saturn gets to its summer solstice in 2017 and the lighting gets even better around the north pole.

NASA also held an interesting Google+ Hangout yesterday (Nov. 4) about Saturn and the Cassini mission that featured Carolyn Porco, director of the Cassini Imaging Team and the Cassini Imaging Central Laboratory for Operations (CICLOPS). The whole video below is worth a watch, but here’s a little tidbit to let you know some of what was talked about:

“If you took all the mass of Saturn’s rings and recomposed it into a moon, it would be no bigger than Enceladus, so it’s a big spectacle coming from little mass,” Porco said. “The main rings are very thin, only about 30 feet [9 meters] thick, no bigger than about 2 stories in a modern day building. Despite the fact they are about 280,000 km [174,000 miles] across.”