Atomic number

Fine Structure Constant

[/caption]

Ever wonder why the periodic table of elements is organized the way it is? Why, for example, does Hydrogen come first? And just what are these numbers that are used to sort them all? They are known as the element’s atomic number, and in the periodic table of elements, the atomic number of an element is the same as the number of protons contained within its nucleus. For example, Hydrogen atoms, which have one proton in their nucleuses, are given an atomic number of one. All carbon atoms contain six protons and therefore have an atomic number of 6. Oxygen atoms contain 8 protons and have an atomic number of 8, and so on. The atomic number of an element never changes, meaning that the number of protons in the nucleus of every atom in an element is always the same.

Arranging elements based on their atomic weight began with Ernest Rutherford in 1911. It was he who first suggested the model for an atom where the majority of its mass and positive charge was contained in a core. This central charge would be roughly equal to half of the atoms total atomic weight. Antonius van den Broek added to this by formerly suggesting that the central charge and number of electrons were equal. Two years later, Henry Moseley and Niels Bohr made further contributions that helped to confirm this. The Bohr model of the atom had the central charge contained in its core, with its electrons circulating it in orbit, much like how the planet in the solar system orbit the sun. Moseley was able to confirm these two hypotheses through experimentation, measuring the wavelengths of photon transitions of various elements while they were inside an x-ray tube. Working with elements from aluminum (which has an atomic number thirteen) to gold (seventy nine), he was able to show that the frequency of these transitions increased with each element studied.

In short, the higher the atomic number (aka. the higher the number of protons), the heavier the element is and the lower it appears on the periodic table. The atomic number of an element is conventionally represented by the symbol Z in physics and chemistry. This is presumably derived from the German word Atomzahl, which means atomic number in English. It is not to be confused with the mass number, which is represented by A. This corresponds to the combined mass of protons and neutrons in the element.

We have written many articles about the atomic number for Universe Today. Here’s an article about the atomic nucleus, and here’s an article about the Atom Models.

If you’d like more info on the Atomic Number, check out NASA’s Atoms and Light Energy Page, and here’s a link to NASA’s Atomic Numbers and Multiplying Factors Page.

We’ve also recorded an entire episode of Astronomy Cast all about the Atom. Listen here, Episode 164: Inside the Atom.

Sources:
NDT Resource Center
Jefferson Lab
Wise Geek
Wiki Answers

What Is Atomic Mass

Faraday's Constant

[/caption]

The answer to ‘what is atomic mass’ is this: the total mass of the protons, neutrons, and electrons in a single atom when it is at rest. This is not to be associated or mistaken for atomic weight. Atomic mass is measured by mass spectrometry. You can figure the molecular mass of an compound by adding the atomic mass of its atoms.

Until the 1960’s chemists and physicists used different atomic mass scales. Chemists used a scale that showed that the natural mixture of oxygen isotopes had an atomic mass 16. Physicists assigned 16 to the atomic mass of the most common oxygen isotope. Problems and inconsistencies arose because oxygen 17 and oxygen 18 are also present in natural oxygen. This created two different tables of atomic mass. A unified scale based on carbon-12 is used to meet the physicists’ need to base the scale on a pure isotope and is numerically close to the chemists’ scale.

Standard atomic weight is the average relative atomic mass of an element in the crust of Earth and its atmosphere. This is what is included in standard periodic tables. Atomic weight is being phased out slowly and being replaced by relative atomic mass. This shift in wording dates back to the 1960’s. It has been the source of much debate largely surrounding the adoption of the unified atomic mass unit and the realization that ‘weight’ can be an inappropriate term. Atomic weight is different from atomic mass in that it refers to the most abundant isotope in an element and atomic mass directly addresses a single atom or isotope.

Atomic mass and standard atomic weight can be so close, in elements with a single dominant isotope, that there is little difference when considering bulk calculations. Large variations can occur in elements with many common isotopes. Both have their place in science today. With advances in our knowledge, even these terms may become obsolete in the future.

We have written many articles about atomic mass for Universe Today. Here’s an article about the atomic nucleus, and here’s an article about the atomic models.

If you’d like more info on the Atomic Mass, check out NASA’s Article on Analyzing Tiny Samples, and here’s a link to NASA’s Article about Atoms, Elements, and Isotopes.

We’ve also recorded an entire episode of Astronomy Cast all about the Atom. Listen here, Episode 164: Inside the Atom.

Sources:
Wikipedia
Windows to Universe
NDT Resource Center